Anomalous Small-Angle X-ray Scattering from a Sulfonated Polystyrene Ionomer

Y. Samuel Ding; Stevan R. Hubbard; Keith O. Hodgson; Richard A. Register; Stuart L. Cooper

doi:10.1021/ma00184a028

Anomalous Small-Angle X-ray Scattering from a Sulfonated Polystyrene Ionomer

Y. Samuel Ding, Stevan R. Hubbard, Keith O. Hodgson, Richard A. Register, Stuart L. Cooper

Research output: Contribution to journal › Article › peer-review

126 Scopus citations

Abstract

Anomalous small-angle X-ray scattering has been employed to study the morphology of a nickel-neutralized sulfonated polystyrene ionomer, with particular emphasis on the characteristic upturn in scattered intensity near zero angle. The results indicate that the zero-order scattering is related to the ionomer's neutralizing cation. Applying the Debye-Bueche random two-phase model to the data indicates that the heterogeneity giving rise to the zero-angle scattering has a much larger length scale and smaller electron density difference than the aggregate-matrix scattering and may be due to an inhomogeneous distribution of isolated ionic groups in the matrix.

Original language	English (US)
Pages (from-to)	1698-1703
Number of pages	6
Journal	Macromolecules
Volume	21
Issue number	6
DOIs	https://doi.org/10.1021/ma00184a028
State	Published - 1988
Externally published	Yes

All Science Journal Classification (ASJC) codes

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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title = "Anomalous Small-Angle X-ray Scattering from a Sulfonated Polystyrene Ionomer",

abstract = "Anomalous small-angle X-ray scattering has been employed to study the morphology of a nickel-neutralized sulfonated polystyrene ionomer, with particular emphasis on the characteristic upturn in scattered intensity near zero angle. The results indicate that the zero-order scattering is related to the ionomer's neutralizing cation. Applying the Debye-Bueche random two-phase model to the data indicates that the heterogeneity giving rise to the zero-angle scattering has a much larger length scale and smaller electron density difference than the aggregate-matrix scattering and may be due to an inhomogeneous distribution of isolated ionic groups in the matrix.",

author = "\{Samuel Ding\}, Y. and Hubbard, \{Stevan R.\} and Hodgson, \{Keith O.\} and Register, \{Richard A.\} and Cooper, \{Stuart L.\}",

year = "1988",

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language = "English (US)",

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journal = "Macromolecules",

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AU - Samuel Ding, Y.

AU - Hubbard, Stevan R.

AU - Hodgson, Keith O.

AU - Register, Richard A.

AU - Cooper, Stuart L.

PY - 1988

Y1 - 1988

N2 - Anomalous small-angle X-ray scattering has been employed to study the morphology of a nickel-neutralized sulfonated polystyrene ionomer, with particular emphasis on the characteristic upturn in scattered intensity near zero angle. The results indicate that the zero-order scattering is related to the ionomer's neutralizing cation. Applying the Debye-Bueche random two-phase model to the data indicates that the heterogeneity giving rise to the zero-angle scattering has a much larger length scale and smaller electron density difference than the aggregate-matrix scattering and may be due to an inhomogeneous distribution of isolated ionic groups in the matrix.

AB - Anomalous small-angle X-ray scattering has been employed to study the morphology of a nickel-neutralized sulfonated polystyrene ionomer, with particular emphasis on the characteristic upturn in scattered intensity near zero angle. The results indicate that the zero-order scattering is related to the ionomer's neutralizing cation. Applying the Debye-Bueche random two-phase model to the data indicates that the heterogeneity giving rise to the zero-angle scattering has a much larger length scale and smaller electron density difference than the aggregate-matrix scattering and may be due to an inhomogeneous distribution of isolated ionic groups in the matrix.

UR - https://www.scopus.com/pages/publications/0024030468

UR - https://www.scopus.com/inward/citedby.url?scp=0024030468&partnerID=8YFLogxK

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M3 - Article

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SN - 0024-9297

VL - 21

SP - 1698

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JO - Macromolecules

JF - Macromolecules

IS - 6

ER -

Anomalous Small-Angle X-ray Scattering from a Sulfonated Polystyrene Ionomer

Abstract

All Science Journal Classification (ASJC) codes

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