Analysis of pyridinium catalyzed electrochemical and photoelectrochemical reduction of CO 2: Chemistry and economic impact

Kate A. Keets, Emily Barton Cole, Amanda J. Morris, Narayanappa Sivasankar, Kyle Teamey, Prasad S. Lakkaraju, Andrew Bruce Bocarsly

Research output: Contribution to journalReview article

10 Scopus citations

Abstract

This review highlights the recent work related to the electrochemical and photoelectrochemical conversion of carbon dioxide into methanol and formic acid. Information related to the structural, mechanistic and kinetic aspects of the pyridinium and imidazolium catalyzed reduction processes is presented. The economic impact of these processes is delineated by calculating the cost per billion gallons of gasoline equivalence for methanol by three methods viz., electrochemical conversion, photoelectrochemical conversion, combined electrochemical conversion and thermal conversion. Our initial analysis shows that the last method may be the most economically feasible method under the existing technologies.

Original languageEnglish (US)
Pages (from-to)1284-1297
Number of pages14
JournalIndian Journal of Chemistry - Section A Inorganic, Physical, Theoretical and Analytical Chemistry
Volume51
Issue number9-10
StatePublished - Sep 1 2012

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Keywords

  • Carbon dioxide reduction
  • Electrochemical reduction
  • Imidazolium catalysed reactions
  • Photoelectrochemical reduction
  • Pyridinium catalysed reactions

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