Alkyne cycloaddition to a titanocene oxide as a route to cyclopentadienyl modification

Iraklis Pappas; Paul J. Chirik

doi:10.1002/anie.201403584

Alkyne cycloaddition to a titanocene oxide as a route to cyclopentadienyl modification

Iraklis Pappas, Paul J. Chirik

Chemistry

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Addition of terminal or internal alkynes to a base-free titanocene oxide results in synthesis of the corresponding oxometallocyclobutene. With appropriate cyclopentadienyl substitution, these compounds undergo reversible C?C reductive elimination offering a unique approach to cyclopenta dienyl modification.

Original language	English (US)
Pages (from-to)	6241-6244
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	53
Issue number	24
DOIs	https://doi.org/10.1002/anie.201403584
State	Published - Jun 10 2014

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

Keywords

cycloaddition
group transfer
oxo ligands
titanium

Access to Document

10.1002/anie.201403584

Cite this

@article{27367db0f2f547018542079d3a9b6cd8,

title = "Alkyne cycloaddition to a titanocene oxide as a route to cyclopentadienyl modification",

abstract = "Addition of terminal or internal alkynes to a base-free titanocene oxide results in synthesis of the corresponding oxometallocyclobutene. With appropriate cyclopentadienyl substitution, these compounds undergo reversible C?C reductive elimination offering a unique approach to cyclopenta dienyl modification.",

keywords = "cycloaddition, group transfer, oxo ligands, titanium",

author = "Iraklis Pappas and Chirik, {Paul J.}",

year = "2014",

month = jun,

day = "10",

doi = "10.1002/anie.201403584",

language = "English (US)",

volume = "53",

pages = "6241--6244",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "24",

}

TY - JOUR

T1 - Alkyne cycloaddition to a titanocene oxide as a route to cyclopentadienyl modification

AU - Pappas, Iraklis

AU - Chirik, Paul J.

PY - 2014/6/10

Y1 - 2014/6/10

N2 - Addition of terminal or internal alkynes to a base-free titanocene oxide results in synthesis of the corresponding oxometallocyclobutene. With appropriate cyclopentadienyl substitution, these compounds undergo reversible C?C reductive elimination offering a unique approach to cyclopenta dienyl modification.

AB - Addition of terminal or internal alkynes to a base-free titanocene oxide results in synthesis of the corresponding oxometallocyclobutene. With appropriate cyclopentadienyl substitution, these compounds undergo reversible C?C reductive elimination offering a unique approach to cyclopenta dienyl modification.

KW - cycloaddition

KW - group transfer

KW - oxo ligands

KW - titanium

UR - http://www.scopus.com/inward/record.url?scp=84902153708&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84902153708&partnerID=8YFLogxK

U2 - 10.1002/anie.201403584

DO - 10.1002/anie.201403584

M3 - Article

C2 - 24796547

AN - SCOPUS:84902153708

SN - 1433-7851

VL - 53

SP - 6241

EP - 6244

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 24

ER -

Alkyne cycloaddition to a titanocene oxide as a route to cyclopentadienyl modification

Abstract

All Science Journal Classification (ASJC) codes

Keywords

Access to Document

Other files and links

Fingerprint

Cite this