Alkyl Isocyanates via Manganese-Catalyzed C-H Activation for the Preparation of Substituted Ureas

Keyphrases

• C-H Activation 100%
• Manganese-catalyzed 100%
• N-substituted Ureas 100%
• Alkyl Isocyanides 100%
• Isocyanate 66%
• Urea 66%
• Room Temperature 33%
• Reaction Mechanism 33%
• Manganese 33%
• EPR Spectroscopy 33%
• Catalytic Conditions 33%
• Alkyl Radicals 33%
• Asymmetric Synthesis 33%
• Aniline 33%
• Enantiomeric Excess 33%
• Organic Isocyanates 33%
• Salen Catalyst 33%
• Synthetic Methods 33%
• Directly Observed 33%
• Aliphatic Isocyanate 33%
• DFT Calculations 33%
• Benzylic C-H Bond 33%
• Good Yields 33%
• Isocyanation 33%
• Functional Group Compatibility 33%

Chemistry

• Isocyanate 100%
• Manganese 100%
• Urea 100%
• Ambient Reaction Temperature 20%
• EPR Spectroscopy 20%
• Asymmetric Synthesis 20%
• Salen 20%
• Enantiomer 20%
• Density Functional Theory 20%
• Catalyst 20%
• Aniline 20%