### Abstract

A set of time-dependent basis states is obtained with a group of unitary transformations generated by a Lie algebra. Applying the time-dependent variational principle to the trial function subspace constructed from the linear combination of the time-dependent basis states gives rise to a set of "classical" equations of motion for the group parameters and the expansion coefficients from which the time evolution of the system state can be determined. The formulation is developed for a general Lie algebra as well as for the commonly encountered algebra containing homogeneous polynominal products of the coordinate Q and momentum P operators (or equivalently the boson creation a^{†} and annihilation a operators) of order 0, 1, and 2. Explicit expressions for the transition amplitudes are derived by virtue of the cannonical transformation properties of the unitary transformation. The applicability of the present formalism in a variety of problems is implied by two illustrative examples: (a) a parametric amplifier; (b) the collinear collision of an atom with a Morse oscillator.

Original language | English (US) |
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Pages (from-to) | 7508-7521 |

Number of pages | 14 |

Journal | The Journal of chemical physics |

Volume | 88 |

Issue number | 12 |

DOIs | |

State | Published - Jan 1 1988 |

### All Science Journal Classification (ASJC) codes

- Physics and Astronomy(all)
- Physical and Theoretical Chemistry

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## Cite this

*The Journal of chemical physics*,

*88*(12), 7508-7521. https://doi.org/10.1063/1.454315