Aerosol-assisted synthesis of submicron particles at room temperature using ultra-fine liquid atomization

Maksim Mezhericher, Janine K. Nunes, Jan J. Guzowski, Howard A. Stone

Research output: Contribution to journalArticle

7 Scopus citations

Abstract

Aerosol-assisted particle technologies are common in commercial atomizing devices for producing micron-sized droplets, which upon evaporation of solvent typically yield particles in the micron to submicron range obtained from a process of droplet-to-particle conversion. In this paper, we demonstrate a technology that allows room-temperature manufacturing of particles O(100–500) nm in diameter by generating and drying of submicron droplet aerosols. As measured for water atomization, the produced droplets of O(200) nm in mean diameter are an order of magnitude smaller than 3–5 µm water droplets usually obtained from commercial atomizers and nebulizers. This reduction in droplet size promotes evaporation of solvent around two orders of magnitude faster than for the droplets produced by conventional atomization devices. Such rapid solvent evaporation enables formation of submicron particles even in the limit of room temperature drying conditions in a compact laboratory-scale setup, as we demonstrate in this study for sodium chloride and silica and titania xerogel particles. Ultra-fine diameters of the generated droplets enable the usage of more concentrated precursor solutions, e.g. ten or even one hundred times, to obtain the same final particle size as conventional aerosol-assisted setups. Based on the experimental study, we establish mathematical expressions correlating the mean particle size and production capacity with solute concentration in the precursor, physical properties of the solution and the atomizing air pressure. Finally, we compare and demonstrate the advantages of the developed system over the existing aerosol-assisted processes in terms of smaller particle size, larger overall and specific production capacities, and higher estimated energy efficiency. The results suggest that this economical and scalable method can be utilized for aerosol-assisted submicron particle synthesis in different applications.

Original languageEnglish (US)
Pages (from-to)606-620
Number of pages15
JournalChemical Engineering Journal
Volume346
DOIs
StatePublished - Aug 15 2018

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Environmental Chemistry
  • Chemical Engineering(all)
  • Industrial and Manufacturing Engineering

Keywords

  • Aerosol-assisted
  • Bubble
  • Drying
  • Submicron droplet
  • Submicron particle
  • Synthesis

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