TY - JOUR
T1 - Additive Growth and Crystallization of Polymer Films
AU - Jeong, Hyuncheol
AU - Shepard, Kimberly B.
AU - Purdum, Geoffrey E.
AU - Guo, Yunlong
AU - Loo, Yueh Lin
AU - Arnold, Craig B.
AU - Priestley, Rodney D.
N1 - Funding Information:
R.D.P., Y.-L.L. and C.B.A. acknowledge support of the National Science Foundation (NSF) Materials Research Science and Engineering Center program through the Princeton Center for Complex Materials (DMR-0819860; DMR-1420541). Portions of this work were conducted at the Cornell High Energy Synchrotron Source (CHESS), which is supported by the National Science Foundation and the National Institutes of Health/National Institute of General Medical Sciences under NSF Awards DMR-0936384 and DMR-1332208. H.J. acknowledges support from Kwanjeong Educational Foundation in South Korea, and G.E.P. acknowledges support from DoD, Air Force Office of Scientific Research, the National Defense Science and Engineering Graduate (NDSEG) Fellowship Program, 32 CFR 168a.
Publisher Copyright:
© 2016 American Chemical Society.
PY - 2016/4/26
Y1 - 2016/4/26
N2 - We demonstrated a polymeric thin film fabrication process in which molecular-scale crystallization proceeds with additive film growth, by employing an innovative vapor-assisted deposition process termed matrix-assisted pulsed laser evaporation (MAPLE). In comparison to solution-casting commonly adopted for the deposition of polymer thin films, this physical vapor deposition (PVD) methodology can prolong the time scale of film formation and allow for the manipulation of temperature during deposition. For the deposition of molecular and atomic systems, such a PVD manner has been demonstrated to facilitate molecular ordering and delicately manipulate crystalline morphology during film growth. Here, using MAPLE, we deposited thin films of a model polymer, poly(ethylene oxide) (PEO), atop a temperature-controlled substrate with an average growth rate of less than 10 nm/h. The mechanism of deposition is sequential addition of nanoscale liquid droplets. We discovered that the deposition process leads to the formation of two-dimensional (2D) PEO crystals, composed of monolamellar crystals laterally grown from larger nucleus droplets. The 2D crystalline coverage and crystal thickness of the films can be manipulated with two processing parameters, deposition time, and temperature.
AB - We demonstrated a polymeric thin film fabrication process in which molecular-scale crystallization proceeds with additive film growth, by employing an innovative vapor-assisted deposition process termed matrix-assisted pulsed laser evaporation (MAPLE). In comparison to solution-casting commonly adopted for the deposition of polymer thin films, this physical vapor deposition (PVD) methodology can prolong the time scale of film formation and allow for the manipulation of temperature during deposition. For the deposition of molecular and atomic systems, such a PVD manner has been demonstrated to facilitate molecular ordering and delicately manipulate crystalline morphology during film growth. Here, using MAPLE, we deposited thin films of a model polymer, poly(ethylene oxide) (PEO), atop a temperature-controlled substrate with an average growth rate of less than 10 nm/h. The mechanism of deposition is sequential addition of nanoscale liquid droplets. We discovered that the deposition process leads to the formation of two-dimensional (2D) PEO crystals, composed of monolamellar crystals laterally grown from larger nucleus droplets. The 2D crystalline coverage and crystal thickness of the films can be manipulated with two processing parameters, deposition time, and temperature.
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U2 - 10.1021/acs.macromol.5b02675
DO - 10.1021/acs.macromol.5b02675
M3 - Article
AN - SCOPUS:84964777769
SN - 0024-9297
VL - 49
SP - 2860
EP - 2867
JO - Macromolecules
JF - Macromolecules
IS - 7
ER -