Activation of alkylidene-bridged heterobimetallic complexes toward electrophilic attack

Susan M. Clift; Jeffrey Schwartz

doi:10.1016/0022-328X(85)87391-5

Activation of alkylidene-bridged heterobimetallic complexes toward electrophilic attack

Susan M. Clift, Jeffrey Schwartz

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Treatment of alkylidene-bridged zirconium-aluminum species with HMPA renders the CAl bond of the alkylidene unit susceptible to electrophilic attack; in the absence of HMPA, the CZr bond is attacked.

Original language	English (US)
Pages (from-to)	C5
Journal	Journal of Organometallic Chemistry
Volume	285
Issue number	1-3
DOIs	https://doi.org/10.1016/0022-328X(85)87391-5
State	Published - Apr 16 1985

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/0022-328X(85)87391-5

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title = "Activation of alkylidene-bridged heterobimetallic complexes toward electrophilic attack",

abstract = "Treatment of alkylidene-bridged zirconium-aluminum species with HMPA renders the CAl bond of the alkylidene unit susceptible to electrophilic attack; in the absence of HMPA, the CZr bond is attacked.",

author = "Clift, {Susan M.} and Jeffrey Schwartz",

year = "1985",

month = apr,

day = "16",

doi = "10.1016/0022-328X(85)87391-5",

language = "English (US)",

volume = "285",

pages = "C5",

journal = "Journal of Organometallic Chemistry",

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T1 - Activation of alkylidene-bridged heterobimetallic complexes toward electrophilic attack

AU - Clift, Susan M.

AU - Schwartz, Jeffrey

PY - 1985/4/16

Y1 - 1985/4/16

N2 - Treatment of alkylidene-bridged zirconium-aluminum species with HMPA renders the CAl bond of the alkylidene unit susceptible to electrophilic attack; in the absence of HMPA, the CZr bond is attacked.

AB - Treatment of alkylidene-bridged zirconium-aluminum species with HMPA renders the CAl bond of the alkylidene unit susceptible to electrophilic attack; in the absence of HMPA, the CZr bond is attacked.

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U2 - 10.1016/0022-328X(85)87391-5

DO - 10.1016/0022-328X(85)87391-5

M3 - Article

AN - SCOPUS:0007642161

SN - 0022-328X

VL - 285

SP - C5

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-3

ER -

Activation of alkylidene-bridged heterobimetallic complexes toward electrophilic attack

Abstract

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