Accurately quantifying clear-sky radiative cooling potentials: A temperature correction to the transmittance-based approximation

Theoretical calculations of the cooling potential of radiative cooling materials are crucial for determining their cooling capability under different meteorological conditions and evaluating their performance. To facilitate these calculations, accurate models of long-wave infrared down-welling atmospheric irradiance are needed. However, the transmittance-based cosine approxima-tion, which is widely used to determine radiative cooling potentials under clear sky conditions, does not account for the cooling potential arising from heat loss to the colder reaches of the atmosphere itself. Here, we show that use of the approximation can lead to >10% underestimation of the cooling potential relative to MODTRAN 6 outputs. We propose a temperature correction to the transmit-tance-based approximation, which accounts for heat loss to the cold upper atmosphere, and signif-icantly reduces this underestimation, while retaining the advantages of the original model. In light of the widespread and continued use of the transmittance-based model, our results highlight an important source of potential errors in the calculation of clear sky radiative cooling potentials and a means to correct for them.