A strong regioregularity effect in self-organizing conjugated polymer films and high-efficiency polythiophene:fullerene solar cells

Youngkyoo Kim; Steffan Cook; Sachetan M. Tuladhar; Stelios A. Choulis; Jenny Nelson; James R. Durrant; Donal D.C. Bradley; Mark Giles; Iain McCulloch; Chang Sik Ha; Moonhor Ree

doi:10.1038/nmat1574

A strong regioregularity effect in self-organizing conjugated polymer films and high-efficiency polythiophene:fullerene solar cells

Youngkyoo Kim
, Steffan Cook
, Sachetan M. Tuladhar
, Stelios A. Choulis
, Jenny Nelson
, James R. Durrant
, Donal D.C. Bradley
, Mark Giles
, Iain McCulloch
, Chang Sik Ha
, Moonhor Ree

Research output: Contribution to journal › Article › peer-review

2319 Scopus citations

Abstract

The influence of polymer regioregularity (RR) on the molecular nanostructure, and on the resulting material properties and device performance was analyzed. Annealed blend films show increased α regardless of RR, that indicates improved charge-carrier diffusion. It was found that the highest device efficiencies will be achieved with the highest RR P3HT. It was also found that the dark-current density of as-fabricated devices made with pristine P3HT increases with the RR of P3HT in the higher voltage regime.

Original language	English (US)
Pages (from-to)	197-203
Number of pages	7
Journal	Nature Materials
Volume	5
Issue number	3
DOIs	https://doi.org/10.1038/nmat1574
State	Published - Mar 17 2006
Externally published	Yes

All Science Journal Classification (ASJC) codes

General Chemistry
General Materials Science
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

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10.1038/nmat1574

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title = "A strong regioregularity effect in self-organizing conjugated polymer films and high-efficiency polythiophene:fullerene solar cells",

abstract = "The influence of polymer regioregularity (RR) on the molecular nanostructure, and on the resulting material properties and device performance was analyzed. Annealed blend films show increased α regardless of RR, that indicates improved charge-carrier diffusion. It was found that the highest device efficiencies will be achieved with the highest RR P3HT. It was also found that the dark-current density of as-fabricated devices made with pristine P3HT increases with the RR of P3HT in the higher voltage regime.",

author = "Youngkyoo Kim and Steffan Cook and Tuladhar, \{Sachetan M.\} and Choulis, \{Stelios A.\} and Jenny Nelson and Durrant, \{James R.\} and Bradley, \{Donal D.C.\} and Mark Giles and Iain McCulloch and Ha, \{Chang Sik\} and Moonhor Ree",

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doi = "10.1038/nmat1574",

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AU - Kim, Youngkyoo

AU - Cook, Steffan

AU - Tuladhar, Sachetan M.

AU - Choulis, Stelios A.

AU - Nelson, Jenny

AU - Durrant, James R.

AU - Bradley, Donal D.C.

AU - Giles, Mark

AU - McCulloch, Iain

AU - Ha, Chang Sik

AU - Ree, Moonhor

PY - 2006/3/17

Y1 - 2006/3/17

N2 - The influence of polymer regioregularity (RR) on the molecular nanostructure, and on the resulting material properties and device performance was analyzed. Annealed blend films show increased α regardless of RR, that indicates improved charge-carrier diffusion. It was found that the highest device efficiencies will be achieved with the highest RR P3HT. It was also found that the dark-current density of as-fabricated devices made with pristine P3HT increases with the RR of P3HT in the higher voltage regime.

AB - The influence of polymer regioregularity (RR) on the molecular nanostructure, and on the resulting material properties and device performance was analyzed. Annealed blend films show increased α regardless of RR, that indicates improved charge-carrier diffusion. It was found that the highest device efficiencies will be achieved with the highest RR P3HT. It was also found that the dark-current density of as-fabricated devices made with pristine P3HT increases with the RR of P3HT in the higher voltage regime.

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JO - Nature Materials

JF - Nature Materials

IS - 3

ER -

A strong regioregularity effect in self-organizing conjugated polymer films and high-efficiency polythiophene:fullerene solar cells

Abstract

All Science Journal Classification (ASJC) codes

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