A simple molecular thermodynamic theory of hydrophobic hydration

Henry S. Ashbaugh; Thomas M. Truskett; Pablo G. Debenedetti

doi:10.1063/1.1436479

A simple molecular thermodynamic theory of hydrophobic hydration

Henry S. Ashbaugh, Thomas M. Truskett, Pablo G. Debenedetti

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114 Scopus citations

Abstract

A study was carried out to examine the still incompletely understood thermodynamics of hydrophobic hydration beginning from a microscopy theory. The theory was extended to describe aqueous mixtures containing nonpolar solutes. The resulting mixture free energy and equations of state (EOS) capture many of the distinguishing thermodynamic features associated with hydrophobic hydration.

Original language	English (US)
Pages (from-to)	2907-2921
Number of pages	15
Journal	Journal of Chemical Physics
Volume	116
Issue number	7
DOIs	https://doi.org/10.1063/1.1436479
State	Published - Feb 15 2002

All Science Journal Classification (ASJC) codes

General Physics and Astronomy
Physical and Theoretical Chemistry

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title = "A simple molecular thermodynamic theory of hydrophobic hydration",

abstract = "A study was carried out to examine the still incompletely understood thermodynamics of hydrophobic hydration beginning from a microscopy theory. The theory was extended to describe aqueous mixtures containing nonpolar solutes. The resulting mixture free energy and equations of state (EOS) capture many of the distinguishing thermodynamic features associated with hydrophobic hydration.",

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AB - A study was carried out to examine the still incompletely understood thermodynamics of hydrophobic hydration beginning from a microscopy theory. The theory was extended to describe aqueous mixtures containing nonpolar solutes. The resulting mixture free energy and equations of state (EOS) capture many of the distinguishing thermodynamic features associated with hydrophobic hydration.

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A simple molecular thermodynamic theory of hydrophobic hydration

Abstract

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