A non-centrosymmetric one-dimensional coordination polymer: Catena[[(4,7-phenanthrolin-4-ium-κN7)(thiocyanato-κS) copper(I)]-μ-thiocyanato-κ2N:S]

Jodi Schottenfeld, Randy S. Rarig, Jon Zubieta, Robert L. Laduca

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Abstract

The title compound, [Cu(NCS)2(C12H9N 2)]n, is a one-dimensional coordination polymer containing tetrahedrally coordinated CuI atoms bound to one N atom from a protonated 4,7-phenanthroline ligand, and one N and two S atoms from three distinct thiocyanate anions. In the crystal structure, chain motifs align parallel to the a axis, formed from the linkage of neighboring CuI atoms through bridging thiocyanate ligands.

Original languageEnglish (US)
Pages (from-to)m278-m280
JournalActa Crystallographica Section E: Structure Reports Online
Volume63
Issue number1
DOIs
StatePublished - Jan 2007
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • General Chemistry
  • General Materials Science
  • Condensed Matter Physics

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