A new approach to indole alkaloids via indole chromium complexes

M. F. Semmelhack; Paul Knochel; T. Singleton

doi:10.1016/S0040-4039(00)60673-1

A new approach to indole alkaloids via indole chromium complexes

M. F. Semmelhack, Paul Knochel, T. Singleton

Chemistry

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

The activating effect of pi complexation of a Cr(CO)₃ unit allows selective nucleophilic substitution in indoles such as tryptophan derivatives and provides intermediates for the synthesis of clavicipitic acid and related indole natural products.

Original language	English (US)
Pages (from-to)	5051-5054
Number of pages	4
Journal	Tetrahedron Letters
Volume	34
Issue number	32
DOIs	https://doi.org/10.1016/S0040-4039(00)60673-1
State	Published - Aug 6 1993

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)60673-1

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title = "A new approach to indole alkaloids via indole chromium complexes",

abstract = "The activating effect of pi complexation of a Cr(CO)3 unit allows selective nucleophilic substitution in indoles such as tryptophan derivatives and provides intermediates for the synthesis of clavicipitic acid and related indole natural products.",

author = "Semmelhack, {M. F.} and Paul Knochel and T. Singleton",

year = "1993",

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AU - Semmelhack, M. F.

AU - Knochel, Paul

AU - Singleton, T.

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Y1 - 1993/8/6

N2 - The activating effect of pi complexation of a Cr(CO)3 unit allows selective nucleophilic substitution in indoles such as tryptophan derivatives and provides intermediates for the synthesis of clavicipitic acid and related indole natural products.

AB - The activating effect of pi complexation of a Cr(CO)3 unit allows selective nucleophilic substitution in indoles such as tryptophan derivatives and provides intermediates for the synthesis of clavicipitic acid and related indole natural products.

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U2 - 10.1016/S0040-4039(00)60673-1

DO - 10.1016/S0040-4039(00)60673-1

M3 - Article

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SN - 0040-4039

VL - 34

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EP - 5054

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 32

ER -

A new approach to indole alkaloids via indole chromium complexes

Abstract

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