Abstract
A generalized technique is presented for the calculation of the pure component parameters for use in a general two-parameter equation of state. The method requires as input data the vapor pressure and saturated liquid volume of a component at a given temperature, and is both accurate and simple to use. Correlations for the calculation of the parameters are presented for the van der Waals, Redlich-Kwong and Peng-Robinson forms of cubic equations of state. A comparison is made between the new method and the corresponding-states approach.
Original language | English (US) |
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Pages (from-to) | 77-88 |
Number of pages | 12 |
Journal | Fluid Phase Equilibria |
Volume | 22 |
Issue number | 1 |
DOIs | |
State | Published - Oct 2 1985 |
Externally published | Yes |
All Science Journal Classification (ASJC) codes
- General Chemical Engineering
- General Physics and Astronomy
- Physical and Theoretical Chemistry