A generalized technique to obtain pure component parameters for two-parameter equations of state

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Abstract

A generalized technique is presented for the calculation of the pure component parameters for use in a general two-parameter equation of state. The method requires as input data the vapor pressure and saturated liquid volume of a component at a given temperature, and is both accurate and simple to use. Correlations for the calculation of the parameters are presented for the van der Waals, Redlich-Kwong and Peng-Robinson forms of cubic equations of state. A comparison is made between the new method and the corresponding-states approach.

Original languageEnglish (US)
Pages (from-to)77-88
Number of pages12
JournalFluid Phase Equilibria
Volume22
Issue number1
DOIs
StatePublished - Oct 2 1985
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • General Chemical Engineering
  • General Physics and Astronomy
  • Physical and Theoretical Chemistry

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