TY - GEN
T1 - A comprehensive evaluation of soret diffusion in heptane-air flames
AU - Xin, Y. X.
AU - Sung, C. J.
AU - Law, C. K.
N1 - Funding Information:
This work was supported by the NASA Microgravity Combustion Program.
Copyright:
Copyright 2015 Elsevier B.V., All rights reserved.
PY - 2011
Y1 - 2011
N2 - The influence of Soret diffusion on the structure and response of n-heptane/air flames is investigated numerically with detailed reaction mechanism and transport. Unstretched freely-propagating planar premixed flames as well as stretched counterflow premixed and diffusion flames are studied, with emphasis on the separate and combined Soret effects of heptane and its oppositely-directed decomposition species H2 and H, as well as those of the major species O2, N2, CO2 and H2O. Results show that, in the unstretched case for which the flame temperature remains at its adiabatic value, Soret diffusion primarily affects the chemical kinetics embedded in the flame structure and the net effect is small; while in the stretched cases, its impact is mainly through those of heptane and the secondary fuel H2 in modifying the flame temperature, with substantial effects, while H2 and H also affect the chemical kinetics especially when the active reaction zone is localized. The dilution/enrichment of the reactant concentrations in the flame through the Soret diffusion of the major species O2, N2, CO2 and H2O further exert finite effects on the flame burning intensity.
AB - The influence of Soret diffusion on the structure and response of n-heptane/air flames is investigated numerically with detailed reaction mechanism and transport. Unstretched freely-propagating planar premixed flames as well as stretched counterflow premixed and diffusion flames are studied, with emphasis on the separate and combined Soret effects of heptane and its oppositely-directed decomposition species H2 and H, as well as those of the major species O2, N2, CO2 and H2O. Results show that, in the unstretched case for which the flame temperature remains at its adiabatic value, Soret diffusion primarily affects the chemical kinetics embedded in the flame structure and the net effect is small; while in the stretched cases, its impact is mainly through those of heptane and the secondary fuel H2 in modifying the flame temperature, with substantial effects, while H2 and H also affect the chemical kinetics especially when the active reaction zone is localized. The dilution/enrichment of the reactant concentrations in the flame through the Soret diffusion of the major species O2, N2, CO2 and H2O further exert finite effects on the flame burning intensity.
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M3 - Conference contribution
AN - SCOPUS:84946771358
T3 - Fall Technical Meeting of the Eastern States Section of the Combustion Institute 2011
SP - 451
EP - 463
BT - Fall Technical Meeting of the Eastern States Section of the Combustion Institute 2011
PB - Combustion Institute
T2 - Fall Technical Meeting of the Eastern States Section of the Combustion Institute 2011
Y2 - 9 October 2011 through 12 October 2011
ER -