17% Efficient Organic Solar Cells Based on Liquid Exfoliated WS2 as a Replacement for PEDOT:PSS

Yuanbao Lin, Begimai Adilbekova, Yuliar Firdaus, Emre Yengel, Hendrik Faber, Muhammad Sajjad, Xiaopeng Zheng, Emre Yarali, Akmaral Seitkhan, Osman M. Bakr, Abdulrahman El-Labban, Udo Schwingenschlögl, Vincent Tung, Iain McCulloch, Frédéric Laquai, Thomas D. Anthopoulos

Research output: Contribution to journalArticlepeer-review

522 Scopus citations

Abstract

The application of liquid-exfoliated 2D transition metal disulfides (TMDs) as the hole transport layers (HTLs) in nonfullerene-based organic solar cells is reported. It is shown that solution processing of few-layer WS2 or MoS2 suspensions directly onto transparent indium tin oxide (ITO) electrodes changes their work function without the need for any further treatment. HTLs comprising WS2 are found to exhibit higher uniformity on ITO than those of MoS2 and consistently yield solar cells with superior power conversion efficiency (PCE), improved fill factor (FF), enhanced short-circuit current (JSC), and lower series resistance than devices based on poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) and MoS2. Cells based on the ternary bulk-heterojunction PBDB-T-2F:Y6:PC71BM with WS2 as the HTL exhibit the highest PCE of 17%, with an FF of 78%, open-circuit voltage of 0.84 V, and a JSC of 26 mA cm−2. Analysis of the cells' optical and carrier recombination characteristics indicates that the enhanced performance is most likely attributed to a combination of favorable photonic structure and reduced bimolecular recombination losses in WS2-based cells. The achieved PCE is the highest reported to date for organic solar cells comprised of 2D charge transport interlayers and highlights the potential of TMDs as inexpensive HTLs for high-efficiency organic photovoltaics.

Original languageEnglish (US)
Article number1902965
JournalAdvanced Materials
Volume31
Issue number46
DOIs
StatePublished - Nov 1 2019
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • General Materials Science
  • Mechanics of Materials
  • Mechanical Engineering

Keywords

  • 2D transition metal disulfides
  • hole transport layers
  • liquid exfoliation
  • MoS
  • nonfullerene organic solar cells
  • WS

Fingerprint

Dive into the research topics of '17% Efficient Organic Solar Cells Based on Liquid Exfoliated WS2 as a Replacement for PEDOT:PSS'. Together they form a unique fingerprint.

Cite this